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Episode 206 Spoilers: Chuck vs. the Ex; 11/10/2008
11/3/08: The episode starts off with a flashback to 2003. Chuck is wearing a Buy More uniform and has showed up at a sorority party at Stanford. It's just after he's been expelled for cheating and everyone is whipsering about is which provokes Chuck to respond that he didn't cheat. He attempts to talk to Jill and eventually Jill does appear long enough to tell Chuck that "it's over" and that she's dating Bryce Larkin now. Back in the present, Chuck is in a hotel conference room and spots Jill. He tries to hide from her, but she finds him anyway. Later, Chuck has taken Jill out to dinner to a restaurant that is full of CIA agents with Sarah acting as the waitress. He's trying to impress Jill when the crew from the Buy More show up and bust his bubble. There's another scene where Chuck is outside Jill's hotel room and she invites him in after she finds out that he hasn't gotten over her. Chuck is listening to Jill talk to the same friend from the flashback when he says something which Jill hears. Chuck flashes on an assassin and the assassin kills someone. Later, Sarah is posing as an Australian scientist at the scientific conference and then the assassin releases a virus at the conference. The assassin later tells Casey and Sarah that he's CIA and there's much more to the mission. From Casting Sides
10/21/08: Chuck runs into his ex-girlfriend Jill (guest star Jordana Brewster) while on a Nerd Herd call. In an attempt to save face, he lies to the girl who broke his heart and tells her that he is more successful than he really is. When Chuck flashes on Jill's boss-a research scientist who may have developed a deadly bio-weapon, he, Sarah and Casey must find out if Jill is involved. Meanwhile at the Buy More, Big Mike nearly chokes to death, which leads company efficiency expert Emmett to implement a mandatory CPR course taught by Captain Awesome. From NBC
10/21/08: Selected Promo Pics from the episode:

Undercover Sarah checks up on Chuck and his ex, Jill and she doesn't look happy.

Sarah and a shaggy Casey monitor the situation.

Sarah looks perturbed as Chuck is on the phone.

Jill looks sad [? or apologetic?].

Chuck and Jill kiss even as she still wears a hazard suit.

More kissing from Chuck and Jill.

So just who is Jill talking to on the walkie-talkie?

Jill injects Chuck with the antedote to the virus.

10/12/08: Dr. Jill Roberts is part of a conference of brilliant scientists who could become test subjects for a deadly virus. Chuck has to ply Jill for information, while Sarah goes undercover as an Australian scientist. From [So Yvonne Strahovski has a chance to speak with her natural accent.]
10/12/08: Jordana Brewster plays Jill, who has gone on to become a successful doctor. From EW
10/11/08: Chuck flashes back to just after getting kicked out of Stanford. He goes to talk to his girlfriend Jill, who breaks up with him and reveals that she's dating Bryce. In the present, Jill and her boss come into the Buy More and Chuck flashes on a bio-weapon when he shakes her boss's hand. From
9/29/08: Chuck's ex-girlfriend Jill turns up. From
9/29/08: Added Episode title. From